I Can't See the Wide Width and Full Width Buttons in My Toolbar
When you have a block selected, you should see the Wide Width and Full Width settings in your block's toolbar.
Or in the Layout tab in the inspector:
If you don't see these settings, this means that the theme you are currently using isn't Gutenberg-ready or isn't Block Editor-ready. This simply means that your theme hasn't enabled some Block Editor features such as the Wide Width and Full Width block options.
To resolve this, you will have to contact your theme author and ask them to update your theme and make it support these new WordPress features.